参考文献
[1]Wang D S，Chen Q A，Lu S M，et al.Asymmetric hydrogenation of heteroarenes and arenes[J].Chemical Reviews，2012，112（4）：2557-2590.
[2]He Y M，Song F T，Fan Q H.Advances in transition metal-catalyzed asymmetric hydrogenation of heteroaromatic compounds[J].Topics in Current Chemistry，2014，343：145-190.
[3]Wiesenfeldt M P，Nairoukh Z，Dalton T，et al.Selective arene hydrogenation for direct access to saturated carbo-and heterocycles[J].Angewandte Chemie International Edition，2019，58（31）：10460-10476.
[4]Knowles W S.Asymmetric hydrogenations （Nobel lecture）[J].Angewandte Chemie International Edition，2002，41（12）：1998-2007.
[5]Noyori R.Asymmetric catalysis：Science and opportunities （Nobel lecture）[J].Angewandte Chemie International Edition，2002，41（12）：2008-2022.
[6]Murata S，Sugimoto T，Matsuura S.Hydrogenation and hydrosilylation of quinoxaline by homogeneous rhodium catalysts[J].Heterocycles，1987，26（3）：763-766.
[7]Noyori R，Hashiguchi S.Asymmetric transfer hydrogenation catalyzed by chiral ruthenium complexes[J].Accounts of Chemical Research，1997，30（2）：97-102.
[8]Ohkuma T，Utsumi N，Tsutsumi K，et al.The hydrogenation/transfer hydrogenation network：Asymmetric hydrogenation of ketones with chiral η6-arene/N-tosylethylenediamine-ruthenium（Ⅱ）catalysts[J].Journal of the American Chemical Society，2006，128（27）：8724-8725.
[9]Luo Y E，He Y M，Fan Q H.Asymmetric hydrogenation of quinoline derivatives catalyzed by cationic transition metal complexes of chiral diamine ligands：Scope，mechanism and catalyst recycling[J].The Chemical Record，2016，16（6）：2697-2711.
[10]Liu Y B，Du H F.Frustrated Lewis pair catalyzed asymmetric hydrogenation[J].Acta Chimica Sinica，2014，72（7）：771-777.
[11]Meng W，Feng X Q，Du H F.Frustrated Lewis pairs catalyzed asymmetric metal-free hydrogenations and hydrosilylations[J].Accounts of Chemical Research，2018，51（1）：191-201.
[12]Liu Y B，Du H F.Chiral dienes as “ligands” for borane-catalyzed metal-free asymmetric hydrogenation of imines[J].Journal of the American Chemical Society，2013，135（18）：6810-6813.
[13]Ren X Y，Li G，Wei S M，et al.Facile development of chiral alkenylboranes from chiral diynes for asymmetric hydrogenation of silyl enol ethers[J].Organic Letters，2015，17（4）：990-993.
[14]Wang W B，Lu S M，Yang P Y，et al.Highly enantioselective iridium-catalyzed hydrogenation of heteroaromatic compounds，quinolines[J].Journal of the American Chemical Society，2003，125（35）：10536-10537.
[15]Zhou H F，Li Z W，Wang Z J，et al.Hydrogenation of quinolines using a recyclable phosphine-free chiral cationic ruthenium catalyst：Enhancement of catalyst stability and selectivity in an ionic liquid[J].Angewandte Chemie International Edition，2008，47（44）：8464-8467.
[16]Wang T L，Zhuo L G，Li Z W，et al.Highly enantioselective hydrogenation of quinolines using phosphine-free chiral cationic ruthenium catalysts：Scope，mechanism，and origin of enantioselectivity[J].Journal of the American Chemical Society，2011，133（25）：9878-9891.
[17]Ding Z Y，Wang T L，He Y M，et al.Highly enantioselective synthesis of chiral tetrahydroquinolines and tetrahydroisoquinolines by ruthenium-catalyzed asymmetric hydrogenation in ionic liquid[J].Advanced Synthesis & Catalysis，2013，355（18）：3727-3735.
[18]Yang Z S，Chen F，He Y M，et al.Efficient asymmetric hydrogenation of quinolines in neat water catalyzed by chiral cationic Ru-diamine complexes[J].Catalysis Science & Technology，2014，4（9）：2887-2890.
[19]Wang Z J，Zhou H F，Wang T L，et al.Highly enantioselective hydrogenation of quinolines under solvent-free or highly concentrated conditions[J].Green Chemistry，2009，11（6）：767-769.
[20]Li Z W，Wang T L，He Y M，et al.Air-stable and phosphine-free iridium catalysts for highly enantioselective hydrogenation of quinoline derivatives[J].Organic Letters，2008，10（22）：5265-5268.
[21]Chen F，Ding Z Y，He Y M，et a.Synthesis of optically active 1，2，3，4-tetrahydroquinolines viaasymmetric hydrogenation using iridium-diamine catalyst[J].Organic Syntheses，2015，92：213-226.
[22]Zhang Z H，Du H F.cis-Selective and highly enantioselective hydrogenation of 2，3，4-trisubstituted quinolines[J].Organic Letters，2015，17（11）：2816-2819.
[23]Zhang Z H，Du H F.Enantioselective metal-free hydrogenations of disubstituted quinolines[J].Organic Letters，2015，17（24）：6266-6269.
[24]Qin J，Chen F，Ding Z Y，et al.Asymmetric hydrogenation of 2-and 2，3-substituted quinoxalines with chiral cationic ruthenium diamine catalysts[J].Organic Letters，2011，13（24）：6568-6571.
[25]Zhang Z H，Du H F.A highly cis-selective and enantioselective metal-free hydrogenation of 2，3-disubstituted quinoxalines[J].Angewandte Chemie International Edition，2015，54（2）：623-626.(https://www.daowen.com)
[26]Li S L，Meng W，Du H F.Asymmetric transfer hydrogenations of 2，3-disubstituted quinoxalines with ammonia borane[J].Organic Letters，2017，19（10）：2604-2606.
[27]Kuwano R，Sato K，Kurokawa T，et al.Catalytic asymmetric hydrogenation of heteroaromatic compounds，indoles[J].Journal of the American Chemical Society，2000，122（31）：7614-7615.
[28]Wang D S，Chen Q A，Li W，et al.Pd-catalyzed asymmetric hydrogenation of unprotected indoles activated by Brønsted acids[J].Journal of the American Chemical Society，2010，132（26）：8909-8911.
[29]Yang Z S，Chen F，He Y M，et al.Highly enantioselective synthesis of indolines：Asymmetric hydrogenation at ambient temperature and pressure with cationic ruthenium diamine catalysts[J].Angewandte Chemie International Edition，2016，55（44）：13863-13866.
[30]Yang Z H，Chen F，Zhang S X，et al.Ruthenium-catalyzed enantioselective hydrogenation of phenanthridine derivatives[J].Organic Letters，2017，19（6）：1458-1461.
[31]Liu Y B，Du H F.Metal-free borane-catalyzed highly stereoselective hydrogenation of pyridines[J].Journal of the American Chemical Society，2013，135（35）：12968-12971.
[32]Chen F，Ding Z Y，Qin J，et al.Highly effective asymmetric hydrogenation of cyclic N-alkyl imines with chiral cationic Ru-MsDPEN catalysts[J].Organic Letters，2011，13（16）：4348-4351.
[33]Chen F，Li Z W，He Y M，et al.Asymmetric hydrogenation of cyclic N-sulfonylimines with phosphine-free chiral cationic Ru-MsDPEN catalysts[J].Chinese Journal of Chemistry，2010，28（9）：1529-1532.
[34]Ding Z Y，Chen F，Qin J，et al.Asymmetric hydrogenation of 2，4-disubstituted 1，5-benzodiazepines using cationic ruthenium diamine catalysts：An unusual achiral counteranion induced reversal of enantioselectivity[J].Angewandte Chemie International Edition，2012，51（23）：5706-5710.
[35]Yang Z S，Ding Z Y，Chen F，et al.Asymmetric hydrogenation of cyclic imines of benzoazepines and benzodiazepines with chiral cationic ruthenium-diamine catalysts[J].European Journal of Organic Chemistry，2017，2017（14）：1973-1977.
[36]Qin J，Chen F，He Y M，et al.Asymmetric hydrogenation of 3-substituted 2H-1，4-benzoxazines with chiral cationic Ru-MsDPEN catalysts：A remarkable counteranion effect[J].Organic Chemistry Frontiers，2014，1（8）：952-955.
[37]Wei S M，Feng X Q，Du H F.A metal-free hydrogenation of 3-substituted 2H-1，4-benzoxazines[J].Organic & Biomolecular Chemistry，2016，14（34）：8026-8029.
[38]Zhang S S，Chen F，He Y M，et al.Asymmetric hydrogenation of dibenzo[c，e ]azepine derivatives with chiral cationic ruthenium diamine catalysts[J].Organic Letters，2019，21（14）：5538-5541.
[39]Wang T L，Chen F，Qin J，et al.Asymmetric ruthenium-catalyzed hydrogenation of 2-and 2，9-substituted 1，10-phenanthrolines[J].Angewandte Chemie International Edition，2013，52（28）：7172-7176.
[40]Ma W P，Zhang J W，Xu C，et al.Highly enantioselective direct synthesis of endocyclic vicinal diamines through chiral Ru（diamine）-catalyzed hydrogenation of 2，2′-bisquinoline derivatives[J].Angewandte Chemie International Edition，2016，55（41）：12891-12894.
[41]Li B，Xu C，He Y M，et al.Asymmetric hydrogenation of bis （quinolin-2-yl）methanes：A direct access to chiral 1，3-diamines[J].Chinese Journal of Chemistry，2018，36（12）：1169-1173.
[42]Zhang J W，Chen F，He Y M，et al.Asymmetric ruthenium-catalyzed hydrogenation of 2，6-disubstituted 1，5-naphthyridines：Access to chiral 1，5-diaza-cis-decalins[J].Angewandte Chemie International Edition，2015，54（15）：4622-4625.
[43]Ma W P，Chen F，Liu Y R，et al.Ruthenium-catalyzed enantioselective hydrogenation of 1，8-naphthyridine derivatives[J].Organic Letters，2016，18（11）：2730-2733.
[44]Wang W，Feng X Q，Du H F.Borane-catalyzed metal-free hydrogenation of 2，7-disubstituted 1，8-naphthyridines[J].Organic & Biomolecular Chemistry，2016，14（28）：6683-6686.
[45]Miao T T，Tian Z Y，He Y M，et al.Asymmetric hydrogenation of in situ generated isochromenylium intermediates by copper/ruthenium tandem catalysis[J].Angewandte Chemie International Edition，2017，56（15）：4135-4139.
[46]Xu C，Feng Y，Li F J，et al.A synthetic route to chiral benzo-fused N-heterocycles viasequential intramolecular hydroamination and asymmetric hydrogenation of anilino-alkynes[J].Organometallics，2019，38（20）：3979-3990.
[47]Chen Y，He Y M，Zhang S S，et al.Rapid construction of structurally diverse quinolizidines，indolizidines，and their analogues viaruthenium-catalyzed asymmetric cascade hydrogenation/reductive amination[J].Angewandte Chemie International Edition，2019，58（12）：3809-3813.
[48]Chen Y，Pan Y X，He Y M，et al.Consecutive intermolecular reductive amination/asymmetric hydrogenation：Facile access to sterically tunable chiral vicinal diamines and N-heterocyclic carbenes[J].Angewandte Chemie International Edition，2019，58（47）：16831-16834.