参考文献
[1]Goldberg S.Use of surface complexation models in soil chemical systems[J].Advances in Agronomy,1992,47:233-329.
[2]van Riemsdijk W H,Hiemstra T.Chapter 8.The CD MUSIC model as a framework for interpreting ion adsorption on metal(hydr)oxide surfaces[M]//Lützenkirchen J.Interface Science and Technology.Amsterdam:Elsevier,2006:251268.
[3]Rabung T,Geckeis H,Kim J I,et al.Sorption of Eu(Ⅲ)on a natural hematite:Application of a surface complexation model[J].Journal of Colloid and Interface Science,1998,208(1):153-161.
[4]Rabung T,Stumpf T,Geckeis H,et al.Sorption of Am(Ⅲ)and Eu(Ⅲ)ontoγ-alumina:Experiment and modelling[J].Radiochimica Acta,2000,88(9/10/11):711-716.
[5]Yang C L,Powell B A,Zhang S D,et al.Surface complexation modeling of neptunium(Ⅴ)sorption to lepidocrocite(γ-FeOOH)[J].Radiochimica Acta,2015,103(10):707-717.
[6]Virtanen S,Bok F,Ikeda-Ohno A,et al.The specific sorption of Np(Ⅴ)on the corundum (α-Al2O3)surface in the presence of trivalent lanthanides Eu(Ⅲ)and Gd(Ⅲ):A batch sorption and XAS study[J].Journal of Colloid and Interface Science,2016,483:334-342.
[7]Naveau A,Monteil-Rivera F,Dumonceau J,et al.Sorption of europium on a goethite surface:Influence of background electrolyte[J].Journal of Contaminant Hydrology,2005,77(1/2):1-16.
[8]Guo Z,Su H Y,Wu W S.Sorption and desorption of uranium(Ⅵ)on silica:Experimental and modeling studies[J].Radiochimica Acta,2009,97(3):133-140.
[9]Guo Z,Wang S R,Shi K L,et al.Experimental and modeling studies of Eu(Ⅲ)sorption on TiO2[J].Radiochimica Acta,2009,97(6):283-289.
[10]Guo Z J,Yan C,Xu J,et al.Sorption of U(Ⅵ)and phosphate onγalumina:Binary and ternary sorption systems[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,336(1/2/3):123-129.
[11]Guo Z,Xu J,Shi K,Tang Y,Wu W,Tao Z.Eu(Ⅲ)adsorption/desorption on Na-bentonite:Experimental and modeling studies[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,339(13):126133.
[12]Guo Z J,Li Y,Wu W S.Sorption of U(Ⅵ)on goethite:Ef fects of p H,ionic strength,phosphate,carbonate and fulvic acid[J].Applied Radiation and Isotopes,2009,67(6):996-1000.
[13]Gaines G L,Thomas H C.Adsorption studies on clay minerals.II.A formulation of the thermodynamics of exchange adsorption[J].The Journal of Chemical Physics,1953,21(4):714718.
[14]Bradbury M H,Baeyens B.A mechanistic description of Ni and Zn sorption on Namontmorillonite Part II:Modelling[J].Journal of Contaminant Hydrology,1997,27(3/4):223248.
[15]Bradbury M H,Baeyens B.Sorption modelling on illite Part I:Titration measurements and the sorption of Ni,Co,Eu and Sn[J].Geochimica et Cosmochimica Acta,2009,73(4):990-1003.
[16]Bradbury M H,Baeyens B.Experimental and modelling studies on the p H buffering of MX-80 bentonite porewater[J].Applied Geochemistry,2009,24(3):419-425.
[17]Bradbury M H,Baeyens B.Experimental measurements and modeling of sorption competition on montmorillonite[J].Geochimica et Cosmochimica Acta,2005,69(17):4187-4197.
[18]Kraepiel A M L,Keller K,Morel F M M.On the acid-base chemistry of permanently charged minerals[J].Environmental Science&Technology,1998,32(19):2829-2838.
[19]Tertre E,Castet S,Berger G,et al.Surface chemistry of kaolinite and Na-montmorillonite in aqueous electrolyte solutions at 25 and 60℃:Experimental and modeling study[J].Geochimica et Cosmochimica Acta,2006,70(18):4579-4599.
[20]Chen Z Y,Jin Q,Guo Z J,et al.Surface complexation modeling of Eu(Ⅲ)and phosphate on Na-bentonite:Binary and ternary adsorption systems[J].Chemical Engineering Journal,2014,256:61-68.
[21]杨子谦.U（Ⅵ）和Th（Ⅳ）在金川膨润土上的吸附[D].兰州：兰州大学，2010.
[22]刘福强，叶远虑，郭宁，等.Eu（Ⅲ）在Na基高庙子膨润土上的吸附作用：实验和构模研究[J].中国科学：化学，2013，43（2）：242252.
[23]Ma F,Jin Q,Li P,et al.Experimental and modelling approaches to Am(Ⅲ)and Np(Ⅴ)adsorption on the Maoming kaolinite[J].Applied Geochemistry,2017,84:325-336.
[24]马锋.Np（Ⅴ）、Am（Ⅲ）、Cs（Ⅰ）在钠基高岭土和钠基伊利石上的吸附行为研究[D].兰州：兰州大学，2017.
[25]Nebelung C,Brendler V.U (Ⅵ)sorption on granite:Prediction and experiments[J].Radiochimica Acta,2010,98(9/10/11):621625.
[26]Dong W M,Tokunaga T K,Davis J A,et al.Uranium(Ⅵ)adsorption and surface complexation modeling onto background sediments from the F-area savannah river site[J].Environmental Science&Technology,2012,46(3):1565-1571.
[27]Coutelot F M,Seaman J C,Baker M.Uranium(Ⅵ)adsorption and surface complexation modeling onto vadose sediments from the Savannah River Site[J].Environmental Earth Sciences,2018,77(4):148.
[28]Bradbury M H,Baeyens B.Predictive sorption modelling of Ni(Ⅱ),Co(Ⅱ),Eu(Ⅱ),Th(Ⅳ)and U(Ⅵ)on MX-80 bentonite and Opalinus Clay:A“bottom-up”approach[J].Applied Clay Science,2011,52(1/2):27-33.
[29]Bruggeman C,Liu D J,Maes N.Influence of Boom Clay organic matter on the adsorption of Eu3+by illite-geochemical modelling using the component additivity approach[J].Radiochimica Acta,2010,98(9/10/11):597-605.
[30]Ding M,Kelkar S,Meijer A.Surface complexation modeling of americium sorption onto volcanic tuf f[J].Journal of Environmental Radioactivity,2014,136:181-187.
[31]Davis J A,Coston J A,Kent D B,et al.Application of the surface complexation concept to complex mineral assemblages[J].Environmental Science&Technology,1998,32(19):2820-2828.
[32]Davis J A,Kent D B.Chapter 5.surface complexation modeling in aqueous geochemistry[M]//Michael F,Art F.Mineral-Water Interface Geochemistry.Boston:De Gruyter,1990:177260.
[33]Davis J A,Meece D E,Kohler M,et al.Approaches to surface complexation modeling of Uranium(Ⅵ)adsorption on aquifer sediments[J].Geochimica et Cosmochimica Acta,2004,68(18):36213641.
[34]Tertre E,Hofmann A,Berger G.Rare earth element sorption by basaltic rock:Experimental data and modeling results using the“Generalised Composite approach”[J].Geochimica et Cosmochimica Acta,2008,72(4):1043-1056.
[35]郭治军，陈宗元，吴王锁，等.Eu（Ⅲ）在北山花岗岩上的吸附作用[J].中国科学：化学，2011，41（5）：907-913.
[36]Jin Q,Wang G,Ge M T,et al.The adsorption of Eu(Ⅲ)and Am(Ⅲ)on Beishan granite:XPS,EPMA,batch and modeling study[J].Applied Geochemistry,2014,47:1724.
[37]Jin Q,Su L,Montavon G,et al.Surface complexation modeling of U(Ⅵ)adsorption on granite at ambient/elevated temperature:Experimental and XPS study[J].Chemical Geology,2016,433:81-91.
[38]Moulin V,Stammose D,Ouzounian G.Actinide sorption at oxide-water interfaces:Application to αalumina and amorphous silica[J].Applied Geochemistry,1992,7:163-166.
[39]Buda R,Banik N L,Kratz J V,et al.Studies of the ternary systems humic substances —kaolinite—Pu(Ⅲ)and Pu(Ⅳ)[J].Radiochimica Acta,2008,96(9/10/11):657-665.
[40]KrˇepelováA,Sachs S,Bernhard G.Influence of humic acid on the Am(Ⅲ)sorption onto kaolinite[J].Radiochimica Acta,2011,99(5):253-260.
[41]Lee M H,Jung E C,Song K,et al.The influence of humic acid on the p H-dependent sorption of americium(Ⅲ)onto kaolinite[J].Journal of Radioanalytical and Nuclear Chemistry,2011,287(2):639-645.
[42]Samadfam M,Jintoku T,Sato S,et al.Effects of humic acid on the sorption of Am(Ⅲ)and Cm(Ⅲ)on kaolinite[J].Radiochimica Acta,2000,88(9/10/11):717-723.
[43]Takahashi Y,Minai Y,Kimura T,et al.Adsorption of europium(Ⅲ)and americium(Ⅲ)on kaolinite and montmorillonite in the presence of humic acid[J].Journal of Radioanalytical and Nuclear Chemistry,1998,234(1/2):277-282.
[44]Ticknor K V,Vilks P,Vandergraaf T T.The effect of fulvic acid on the sorption of actinides and fission products on granite and selected minerals[J].Applied Geochemistry,1996,11(4):555-565.
[45]Bradbury M H,Baeyens B.Modelling sorption data for the actinides Am(Ⅲ),Np(Ⅴ)and Pa(Ⅴ)on montmorillonite[J].Radiochimica Acta,2006,94(9/10/11):619-625.
[46]Nagasaki S,Tanaka S,Suzuki A.Affinity of finely dispersed montmorillonite colloidal particles for americium and lanthanides[J].Journal of Nuclear Materials,1997,244(1):29-35.
[47]Kumar S,Pente A S,Bajpai R K,et al.Americium sorption on smectite-rich natural clay from granitic ground water[J].Applied Geochemistry,2013,35:2834.
[48]Nagasaki S,Tanaka S,Suzuki A.Colloid formation and sorption of americium in the water/bentonite system[J].Radiochimica Acta,1994,66/67(s1):207-212.
[49]Nagasaki S,Ahn J,Tanaka S,et al.Sorption behavior of Np(Ⅳ),Np(Ⅴ)and Am(Ⅲ)in the disturbed zone between engineered and natural barriers[J].Journal of Radioanalytical and Nuclear Chemistry,1996,214(5):381-389.
[50]Kozai N,Yamasaki S,Ohnuki T.Application of simplified desorption method to study on sorption of americium(Ⅲ)on bentonite[J].Journal of Radioanalytical and Nuclear Chemistry,2014,299(3):1571-1579.
[51]Iijima K,Shoji Y,Tomura T.Sorption behavior of americium onto bentonite colloid[J].Radiochimica Acta,2008,96(9/10/11):721-730.
[52]Murali M,Mathur J.Sorption characteristics of Am(Ⅲ),Sr(Ⅱ)and Cs(Ⅰ)on bentonite and granite[J].Journal of Radioanalytical and Nuclear Chemistry,2002,254(1):129-136.
[53]Bradbury M H,Baeyens B.Sorption modelling on illite.Part II:Actinide sorption and linear free energy relationships[J].Geochimica et Cosmochimica Acta,2009,73(4):1004-1013.
[54]Maes N,Aertsens M,Salah S,et al.Cs,Sr and Am retention on argillaceous host rocks:Comparison of data from batch sorption tests and diffusion experiments[M].Belgian:Belgian Nuclear Research Centre,2009.
[55]Degueldre C,Ulrich H J,Silby H.Sorption of241Am onto montmorillonite,illite and hematite colloids[J].Radiochimica Acta,1994,65(3):173180.
[56]Kitamura A,Yamamoto T,Nishikawa S,et al.Sorption behavior of Am(Ⅲ)onto granite[J].Journal of Radioanalytical and Nuclear Chemistry,1999,239(3):449-453.
[57]Lee S G,Lee K Y,Cho S Y,et al.Sorption properties of152Eu and241Am in geological materials:Eu as an analogue for monitoring the Am behavior in heterogeneous geological environments[J].Geosciences Journal,2006,10(2):103-114.
[58]Baik M H,Cho W J,Hahn P S.Research papers:Effects of speciation and carbonate on the sorption of Eu(Ⅲ)onto granite[J].Environmental Engineering Research,2004,9(4):160-167.
[59]Snow M S,Zhao P H,Dai Z R,et al.Neptunium(Ⅴ)sorption to goethite at attomolar to micromolar concentrations[J].Journal of Colloid and Interface Science,2013,390(1):176-182.
[60]Baumer T,Hixon A E.Kinetics of neptunium sorption and desorption in the presence of aluminum(hydr)oxide minerals:Evidence for multi-step desorption at low p H[J].Journal of Environmental Radioactivity,2019,205/206:72-78.
[61]Amayri S,Jermolajev A,Reich T.Neptunium(Ⅴ)sorption on kaolinite[J].Radiochimica Acta,2011,99(6):349-357.
[62]Schmeide K,Bernhard,G.Sorption of Np(Ⅴ)and Np(Ⅳ)onto kaolinite:effects of p H,ionic strength,carbonate and humic acid.Applied Geochemistry,2010,25:12381247.
[63]Niitsu Y,Sato S,Ohashi H,et al.Effects of humic acid on the sorption of neptunium(Ⅴ)on kaolinite[J].Journal of Nuclear Materials,1997,248:328-332.
[64]Mironenko M V,Malikov D A,Kulyako Y M,et al.Sorption of Np(Ⅴ)on kaolinite from solutions of MgCl2and CaCl2[J].Radiochemistry,2006,48(1):62-68.
[65]Zavarin M,Powell B A,Bourbin M,et al.Np(Ⅴ)and Pu(Ⅴ)ion exchange and surfacemediated reduction mechanisms on montmorillonite[J].Environmental Science&Technology,2012,46(5):2692-2698.
[66]Benedicto A,Begg J D,Zhao P,et al.Effect of major cation water composition on the ion exchange of Np(Ⅴ)on montmorillonite:
Na+__K+__Ca2+_Mg2+selectivity coefficients[J].Applied Geochemistry,2014,47:177185.
[67]Turner D R,Pabalan R T.Neptunium(Ⅴ)sorption on montmorillonite:An experimental and surface complexation modeling study[J].Clays and Clay Minerals,1998,46(3):256-269.
[68]Runde W,Conradson S D,Wes Efurd D,et al.Solubility and sorption of redox-sensitive radionuclides(Np,Pu)in J-13 water from the Yucca Mountain site:Comparison between experiment and theory[J].Applied Geochemistry,2002,17(6):837-853.
[69]Mironenko M V,Malikov D A,Kulyako Y M,et al.Sorption of Np(Ⅴ)on montmorillonite from solutions of MgCl2and CaCl2[J].Radiochemistry,2006,48(1):69-74.
[70]Kasar U M,Joshi A R,Patil S K.Controlled-potential coulometric studies on fluoride and sulphate complexes of neptunium(Ⅵ)[J].Journal of Radioanalytical and Nuclear Chemistry,1984,81(1):109-115.
[71]Aksoyoglu S,Burkart W,Goerlich W.Sorption of neptunium on clays[J].Journal of Radioanalytical and Nuclear Chemistry,1991,149(1):119122.
[72]Kozai N,Ohnuki T,Muraoka S.Sorption characteristics of neptunium by sodium-smectite[J].Journal of Nuclear Science and Technology,1993,30(11):1153-1159.
[73]Nagasaki S,Tanaka S,Suzuki A.Geochemical behavior of actinides in high-level radioactive waste disposal[J].Progress in Nuclear Energy,1998,32(1/2):141-161.
[74]Nagasaki S,Tanaka S,Suzuki A.Sorption of neptunium on bentonite and its migration in geosphere[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1999,155(2/3):137-143.
[75]Pratopo M I,Yamaguchi T,Moriyama H,et al.Sorption and colloidal behavior of Np(Ⅳ)in a bentonite-carbonate solution system[J].Journal of Nuclear Science and Technology,1993,30(6):560-566.
[76]Sabodina M N,Kalmykov S N,Sapozhnikov Y A,et al.Neptunium,plutonium and137Cs sorption by bentonite clays and their speciation in pore waters[J].Journal of Radioanalytical and Nuclear Chemistry,2006,270(2):349-355.
[77]Marsac R,lal Banik N,Lützenkirchen J,et al.Neptunium redox speciation at the illite surface[J].Geochimica et Cosmochimica Acta,2015,152:3951.
[78]Banik N L,Marsac R,Lützenkirchen J,et al.Neptunium sorption and redox speciation at the illite surface under highly saline conditions[J].Geochimica et Cosmochimica Acta,2017,215:421431.
[79]Hart K P,Payne T E,Robinson B J,et al.Neptunium uptake on boom clay-time dependence and association of Np with fine particles[J].Radiochimica Acta,1994,66/67(s1):19-22.
[80]Fröhlich D R,Amayri S,Drebert J,et al.Speciation of Np(Ⅴ)uptake by Opalinus Clay using synchrotron microbeam techniques[J].Analytical and Bioanalytical Chemistry,2012,404(8):2151-2162.
[81]Fröhlich D R,Amayri S,Drebert J,et al.Sorption of neptunium(Ⅴ)on Opalinus Clay under aerobic/anaerobic conditions[J].Radiochimica Acta,2011,99(2):71-77.
[82]Fröhlich D R,Amayri S,Drebert J,et al.Influence of temperature and background electrolyte on the sorption of neptunium(Ⅴ)on Opalinus Clay[J].Applied Clay Science,2012,69:43-49.
[83]曾继述，夏德迎.237Np，239Pu，241Am 在膨润土和矿物上的吸附[J].核化学与放射化学，1992，14（1）：49-52.
[84]安永锋，李书绅，李伟娟，等.中国黄土对241Am 吸附特性的实验研究[J].辐射防护，2003，23（6）：372-377.
[85]刘期凤，廖家莉，张东，等.包气带土壤对Eu（Ⅲ）的吸附[J].核化学与放射化学，2005，27（4）：210-215.
[86]章英杰，冯孝贵，梁俊福，等.Am（Ⅲ）在Al2O3和石英上的吸附行为[J].核化学与放射化学，2009，31（2）：72-78.
[87]章英杰，冯孝贵，梁俊福，等.Am（Ⅲ）在花岗岩上的吸附行为[J].原子能科学技术，2009，43（3）：215-220.
[88]章英杰，冯孝贵，梁俊福，等.Am（Ⅲ）在铁氧化物上的吸附行为[J].核化学与放射化学，2009，31（1）：10-15.
[89]周舵，龙浩骑，贯鸿志.2009.Am 在花岗岩上的吸附.核科学技术，391-392.
[90]Tan X L,Fan Q H,Wang X K,et al.Eu(Ⅲ)sorption to TiO2(anatase and rutile):Batch,XPS,and EXAFS studies[J].Environmental Science&Technology,2009,43(9):31153121.
[91]Chen C L,Yang X,Wei J,et al.Eu(Ⅲ)uptake on rectorite in the presence of humic acid:A macroscopic and spectroscopic study[J].Journal of Colloid and Interface Science,2013,393:249256.
[92]Tao Z Y,Li W J,Zhang F M,et al.Adsorption of Am(Ⅲ)on red earth and natural hematite[J].Journal of Radioanalytical and Nuclear Chemistry,2006,268(3):563-568.
[93]丁国清，张茂林，吴王锁.几种有机物对Al2O3吸附Eu（Ⅲ）和Am（Ⅲ）的影响[J].核化学与放射化学，2006，28（4）：240-243.
[94]张茂林.Am（Ⅲ）和Eu（Ⅲ）在凹凸棒石及氧化铝上的吸附行为研究[D].兰州：兰州大学，2008.
[95]Niu Z L,Ohnuki T,Simoni E,et al.Effects of dissolved and fixed humic acid on Eu(Ⅲ)/Yb(Ⅲ)adsorption on aluminum hydroxide:A batch and spectroscopic study[J].Chemical Engineering Journal,2018,351:203-209.
[96]于涛.Eu（Ⅲ）和Am（Ⅲ）在红壤及膨润土上的吸附行为研究[D].兰州：兰州大学，2012.
[97]Jin Q,Wang G,Ge M T,et al.The adsorption of Eu(Ⅲ)and Am(Ⅲ)on Beishan granite:XPS,EPMA,batch and modeling study[J].Applied Geochemistry,2014,47:17-24.
[98]李平.Eu（Ⅲ）、Th（Ⅳ）、U（Ⅵ）在铁氧化物及Np（Ⅴ）在钠基膨润土上的吸附行为研究[D].兰州：兰州大学，2015.
[99]马锋，靳强，高鹏元，等.Np（Ⅴ）在漳州伊利石上吸附作用的实验及建模研究[J].原子能科学技术，2017，51（5）：790-797.
[100]王波，刘德军，姚军，等.激光光谱法研究水溶液中超铀核素化学形态现状[J].辐射防护，2007，27（4）：241250.
[101]Ha J,Trainor T P,Farges F,et al.Interaction of Zn(Ⅱ)with hematite nanoparticles and microparticles:Part 2.ATR-FTIR and EXAFS study of the aqueous Zn(Ⅱ)/oxalate/hematite ternary system[J].Langmuir:the ACS Journal of Surfaces and Colloids,2009,25(10):5586-5593.
[102]Lefèvre G.In situ Fourier-transform infrared spectroscopy studies of inorganic ions adsorption on metal oxides and hydroxides[J].Advances in Colloid and Interface Science,2004,107(2/3):109-123.
[103]Van Loon L R,Soler J M,Bradbury M H.Diffusion of HTO,36Cl-and125I-in Opalinus Clay samples from Mont Terri.Effect of confining pressure[J].Journal of Contaminant Hydrology,2003,61(1/2/3/4):73-83.
[104]Grambow B,Landesman C,Ribet S.Nuclear waste disposal:I.Laboratory simulation of repository properties[J].Applied Geochemistry,2014,49:237-246.
[105]Shackelford C D,Moore S M.Fickian diffusion of radionuclides for engineered containment barriers:Diffusion coefficients,porosities,and complicating issues[J].Engineering Geology,2013,152(1):133-147.
[106]Neretnieks I.Diffusion in the rock matrix:An important factor in radionuclide retardation? [J].Journal of Geophysical Research:Solid Earth,1980,85(B8):4379-4397.
[107]Albinsson Y,Engkvist I.Diffusion of Am,Pu,U,Np,Cs,I and Tc in compacted sandbentonite mixture[J].Radioactive waste management and the nuclear fuel cycle,1991,15(4):221-239.
[108]Albinsson Y,Christiansen-Sätmark B,Engkvist I,et al.Transport of actinides and Tc through a bentonite backfill containing small quantities of iron or copper[J].Radiochimica Acta,1991,52/53(1):283-286.
[109]Ahn J,Suzuki A.Diffusion of the241Am →237Np decay chain limited by their elemental solubilities in the artificial barriers of high-level radioactive waste repositories[J].Nuclear Technology,1993,101(1):79-91.
[110]Sawaguchi T,Yamaguchi T,Iida Y,et al.Diffusion of Cs,Np,Am and Co in compacted sandbentonite mixtures:Evidence for surface diffusion of Cs cations[J].Clay Minerals,2013,48(2):411-422.
[111]Pope R,Powell B.Diffusion of Np(Ⅴ)through a compact engineered clay barrier under repository conditions[C]//Washington:Abstracts of Papers of the American Chemical Society,2016,251.
[112]Wang X K,Montavon G,Grambow B.A new experimental design to investigate the concentration dependent diffusion of Eu(Ⅲ)in compacted bentonite[J].Journal of Radioanalytical and Nuclear Chemistry,2003,257(2):293297.
[113]Wang X K,Chen Y X,Wu Y C.Diffusion of Eu(Ⅲ)in compacted bentonite—Effect of p H,solution concentration and humic acid[J].Applied Radiation and Isotopes,2004,60(6):963-969.
[114]李兵，朱海军，廖家莉，等.腐殖质与铀和超铀元素相互作用的研究进展[J].化学研究与应用，2007，19（12）：1289-1295.
[115]陶祖贻，陆长青.核素迁移和腐殖酸[J].核化学与放射化学，1992，14（2）：120-125.
[116]Bryan N D,Abrahamsen L,Evans N,et al.The effects of humic substances on the transport of radionuclides:Recent improvements in the prediction of behaviour and the understanding of mechanisms[J].Applied Geochemistry,2012,27(2):378-389.
[117]王会，柴之芳，王东琪.腐殖酸与锕系金属离子相互作用的研究进展[J].无机化学学报，2014，30（1）：37-52.
[118]Tiwari J,Ramanathan A,Bauddh K,Korstad J.Humic substances:Structure,function and benefits for agroecosystems—a review[J].Pedosphere,2023,33(2):237-249.
[119]章英杰，赵欣，魏连生，等.Am（Ⅲ）与腐殖酸配位行为的研究[J].核化学与放射化学，1998，20（3）：152-157.
[120]Müller K,Sasaki T.Complex formation of Np(Ⅴ)with fulvic acid at tracer metal concentration[J].Radiochimica Acta,2013,101:1-6.
[121]Kim J I,Sekine T.Complexation of neptunium(Ⅴ)with humic acid[J].Radiochimica Acta,1991,55(4):187-192.
[122]Marquardt C,Kim J I.Complexation of Np(Ⅴ)with fulvic acid[J].Radiochimica Acta,1998,81(3):143-148.
[123]Rao L F,Choppin,G R.Thermodynamic study of the complexation of neptunium(Ⅴ)with humic acids[J].Radiochimica Acta,1995,69(2):87-96.
[124]Seibert A,Mansel A,Marquardt C M,et al.Complexation behaviour of neptunium with humic acid[J].Radiochimica Acta,2001,89(8):505-510.
[125]Marquardt C,Herrmann G,Trautmann N.Complexation of neptunium(Ⅴ)with humic acids at very low metal concentrations[J].Radiochimica Acta,1996,73(3):119-126.
[126]Tochiyama O,Yoshino H,Kubota T,et al.Complex formation of Np(Ⅴ)with humic acid and polyacrylic acid[J].Radiochimica Acta,2000,88(9/10/11):547552.
[127]Buckau G,Kim J I,Klenze R,et al.A comparative spectroscopic study of the fulvate complexation of trivalent transuranium ions[J].Radiochimica Acta,1992,57(2/3):105-112.
[128]Bidoglio G.et al.Complexation of Eu and Tb with fulvic acids as studied by time-resolved laserinduced fluorescence[J].Talanta,1991,38(9):999-1008.
[129]Czerwinski K R,Buckau G,Scherbaum F,et al.Complexation of the uranyl ion with aquatic humic acid[J].Radiochimica Acta,1994,65(2):111120.
[130]Nagao S,Aoyama M,Watanabe A,et al.Complexation of Am with size-fractionated soil humic acids[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,347(1/2/3):239-244.
[131]Wall N A,Borkowski M,Chen J,et al.Complexation of americium with humic,fulvic and citric acids at high ionic strength[J].Radiochimica Acta,2002,90(9/10/11):563-568.
[132]Schmeide K,Reich T,Sachs S,et al.Neptunium(Ⅳ)complexation by humic substances studied by X-ray absorption fine structure spectroscopy[J].Radiochimica Acta,2005,93(4):187-196.
[133]Fröhlich D R,Skerencak-Frech A,Gast M,et al.Fulvic acid complexation of Eu(Ⅲ)and Cm(Ⅲ)at elevated temperatures studied by time-resolved laser fluorescence spectroscopy[J].Dalton Transactions,2014,43(41):1559315601.
[134]史英霞，郭亮天.腐殖酸胶体对超铀核素存在形态的影响研究[J].核化学与放射化学，2003，25（1）：22-25.
[135]Gustafsson,J.P.2013.Visual MINTEQ version 3.1.http://vminteq.lwr.kth.se/visual-minteqver-3-1/,KTH,Sweden.
[136]Gustafsson,J.P.Modeling the acid-base properties and metal complexation of humic substances with the Stockholm humic model[J].Journal of Colloid and Interface Science,2001,244(1):102-112.
[137]Aeschbacher M,Vergari D,Schwarzenbach R P,et al.Electrochemical analysis of proton and electron transfer equilibria of the reducible moieties in humic acids[J].Environmental Science&Technology,2011,45(19):83858394.
[138]魏连生，赵燕菊，孔令琴，等.在模拟地下水中腐殖酸还原钚的行为研究[J].核化学与放射化学，1993，15（4）：234-239.
[139]AndréC,Choppin G R.Reduction of Pu(Ⅴ)by humic acid[J].Radiochimica Acta,2000,88(9/10/11):613-618.
[140]Schmeide K,Sachs S,Bernhard G.Np(Ⅴ)reduction by humic acid:Contribution of reduced sulfur functionalities to the redox behavior of humic acid[J].The Science of the Total Environment,2012,419:116-123.
[141]Shcherbina N S,Kalmykov St N,Perminova I V,et al.Reduction of actinides in higher oxidation states by hydroquinone-enriched humic derivatives[J].Journal of Alloys and
[142]S Ctoe v mepnosuonnd sF,J2,0 0K7r,a s 4t4a4n/o4v4 5S: 5A1,8A-r5d2a1k.ani M S.Formation constants of Cu2+complexes with humic and fulvic acids[J].Geoderma,1973,9:129-141.
[143]杜金洲，高焕新，栾新福，等.电位滴定法研究巩县风化煤黄腐酸的解离与配位作用[J].核化学与放射化学，1994，16（3）：135-141.
[144]杜金洲，井琦，褚泰伟，等.大亚湾腐殖酸与铀酰的络合形成常数测定[J].辐射防护通讯，1994，14（4）：9093.
[145]杨春文.腐殖质与Ca2+、Mg2+、Co2+、Ni2+的络合作用及其在农业中的应用[J].西北民族大学学报（自然科学版），2003，24（3）：67-73.
[146]Koopal L K,Saito T,Pinheiro J P,et al.Ion binding to natural organic matter:General considerations and the NICA-Donnan model[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2005,265(1/2/3):40-54.
[147]Koopal L K,van Riemsdijk W H,de Wit J C M,et al.Analytical isotherm equations for multicomponent adsorption to heterogeneous surfaces[J].Journal of Colloid and Interface Science,1994,166(1):51-60.
[148]Kinniburgh D G,van Riemsdijk W H,Koopal L K,et al.Ion binding to natural organic matter:Competition,heterogeneity,stoichiometry and thermodynamic consistency[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1999,151(1/2):147-166.
[149]Keizer M,Van Riemsdijk W.A computer program for the equilibrium calculation of speciation and transport in soil-water systems(Version 4.6)[R].Department of soil quality,Wageningen University,1999.
[150]Kinniburgh D G.Fit User Guide Technical Report WD/93/23[R].British Geological Survey,Keyworth,Nottinghamshire,1993.
[151]Milne C J,Kinniburgh D G,Tipping E.Generic NICA-Donnan model parameters for proton binding by humic substances[J].Environmental Science&Technology,2001,35(10):2049-2059.
[152]Kinniburgh D G,Milne C J,Benedetti M F,et al.Metal ion binding by humic acid:Application of the NICA-donnan model[J].Environmental Science&Technology,1996,30(5):1687-1698.
[153]Tipping E,Lofts S,Sonke J E.Humic Ion-Binding Model VII:A revised parameterisation of cation-binding by humic substances[J].Environmental Chemistry,2011,8(3):225.
[154]Tipping E.Modelling ion binding by humic acids[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1993,73:117-131.
[155]Tipping E,Hurley M A.A unifying model of cation binding by humic substances[J].Geochimica et Cosmochimica Acta,1992,56(10):3627-3641.
[156]Tipping E,Rey-Castro C,Bryan S E,et al.Al(Ⅲ)and Fe(Ⅲ)binding by humic substances in freshwaters,and implications for trace metal speciation[J].Geochimica et Cosmochimica Acta,2002,66(18):3211-3224.
[157]Peters A J,Hamilton-Taylor J,Tipping E.Americium binding to humic acid[J].Environmental Science&Technology,2001,35(17):3495-3500.
[158]Tipping E.Humic ion-binding model VI:An improved description of the interactions of protons and metal ions with humic substances[J].Aquatic Geochemistry,1998,4(1):347.
[159]Takahashi Y,Kimura T,Minai Y.Direct observation of Cm(Ⅲ)-fulvate species on fulvic acidmontmorillonite hybrid by laser-induced fluorescence spectroscopy [J].Geochimica et Cosmochimica Acta,2002,66(1):1-12.
[160]叶远虑.富里酸存在下U（Ⅵ）、Th（Ⅳ）和Eu（Ⅲ）在SiO2、TiO2及钠基膨润土上的吸附作用[D].兰州：兰州大学，2014.
[161]Wang C L,Yang X Y,Li C,et al.The sorption interactions of humic acid onto Beishan granite[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2015,484:37-46.
[162]魏世勇，谭文峰，刘凡.土壤腐殖质—矿物质交互作用的机制及研究进展[J].中国土壤与肥料，2009（1）：1-6.
[163]吴宏海，张秋云，方建章，等.高岭石和硅/铝-氧化物对腐殖酸的吸附实验研究[J].岩石矿物学杂志，2003，22（2）：173-176.
[164]Kar A,Tomar B.Cm(Ⅲ)sorption by silica:Effect of alpha hydroxy isobutyric acid[J].Radiochimica Acta,2014,102(9):763773.
[165]Janot N,Benedetti M F,Reiller P E.Colloidalα-Al2O3,europium(Ⅲ)and humic substances interactions:A macroscopic and spectroscopic study[J].Environmental Science&Technology,2011,45(8):3224-3230.
[166]Sakamoto Y,Nagao S,Ogawa H,et al.The migration behavior of Np(Ⅴ)in sandy soil and granite media in the presence of humic substances[J].Radiochimica Acta,2000,88(9/10/11):651657.
[167]De Regge P,Henrion P,Monsecour M,et al.Facts and features of radionuclide migration in Boom Clay[J].Radioactive Waste Management Nuclear Fuel Cycle,1988,10(1-3):1-20.
[168]Chunli L,Zhiming W,Li SS,et al.The migration of radionuclides237Np,238Pu and241Am in a weak loess aquifer:A field column experiment.[J].Radiochimica Acta,2001,89(8):519-522.
[169]王旭东，刘志辉，游志均，等.腐殖酸对237Np在石英砂柱中迁移的影响研究[J].辐射防护，2004，24（6）：383-387.
[170]Yang J W,Ge M T,Jin Q,et al.Co-transport of U(Ⅵ),humic acid and colloidal gibbsite in water-saturated porous media[J].Chemosphere,2019,231:405-414.
[171]Yang J W,Zhang Z,Chen Z Y,et al.Co-transport of U(Ⅵ)and gibbsite colloid in saturated granite particle column:Role of p H,U(Ⅵ)concentration and humic acid[J].Science of the Total Environment,2019,688:450-461.
[172]徐国庆.高放废物地质处置地下实验室研究进展[C]//高放废物地质处置学术研讨会，2004.
[173]Vejmelka P,Fanghänel T,Kienzler B,et al.Sorption and migration of radionuclides in granite(HRLÄspö,Sweden)[C]//Forschungszentrum Karlsruhe,FZKA,2000,6488.
[174]Widestrand H,Andersson P,Byegård J,et al.In situ migration experiments atÄspöHard Rock Laboratory,Sweden:Results of radioactive tracer migration studies in a single fracture[J].Journal of radioanalytical and nuclear chemistry,2001,250(3):501-517.
[175]徐国庆.核废物的模拟处置库—地下实验室[J].国外铀金地质，1992，9（S1）：57-69.
[176]Degueldre C,Baeyens B,Goerlich W,et al.Colloids in water from a subsurface fracture in granitic rock,Grimsel Test Site,Switzerland[J].Geochimica et Cosmochimica Acta,1989,53(3):603-610.
[177]Möri A,Alexander W R,Geckeis H,et al.The colloid and radionuclide retardation experiment at the Grimsel Test Site:Influence of bentonite colloids on radionuclide migration in a fractured rock[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2003,217(1/2/3):33-47.
[178]Gillow J B,Dunn M,Francis A J,et al.The potential of subterranean microbes in facilitating actinide migration at the Grimsel Test Site and Waste Isolation Pilot Plant[J].Radiochimica Acta,2000,88(9/10/11):769-775.
[179]Quinto F,Blechschmidt I,Garcia Perez C,et al.Multiactinide analysis with accelerator mass spectrometry for ultratrace determination in small samples: Application to an in situ radionuclide tracer test within the colloid formation and migration experiment at the grimsel test site(Switzerland)[J].Analytical Chemistry,2017,89(13):7182-7189.
[180]Hu Q H,Möri A.Radionuclide transport in fractured granite interface zones[J].Physics and Chemistry Earth,Parts A/B/C,2008,33(14/15/16):1042-1049.
[181]Valcke E,Gysemans M,Moors H,et al.Leaching and migration of Np,Pu,and Am from adoped SON68 HLW glass in contact with dense clay[J].MRS Online Proceedings Library,2006,932(1):91.
[182]Maes N,Wang L,Hicks T,et al.The role of natural organic matter in the migration behaviour of americium in the Boom Clay— Part I:Migration experiments[J].Physics and Chemistry Earth,Parts A/B/C,2006,31(10/11/12/13/14):541-547.
[183]Bruggeman C,Salah S,Maes N.Americium retention and migration behaviour in Boom Clay[C]//External Report of the Belgian Nuclear Research Centre,SCK· CENER-201,Mol,Belgium,2012.
[184]Bruneel Y,Van Laer L,Brassinnes S,et al.Radiocaesium sorption on natural glauconite sands is unexpectedly as strong as on Boom Clay[J].The Science of the Total Environment,2020,720:137392.
[185]Henrion P N,Monsecour M,Put M.Migration studies of radionuclides in boom clay[J].Engineering Geology,1985,21(3/4):311-319.
[186]Dierckx A,Put M,De Cannière P,et al.TRANCOM CLAY Transport of radionuclides due to complexation with organic matter in clay formations[C]//CEC Nuclear Science&Technology Series,Luxembourg,EUR 19135EN,2000.
MOLECULAR SCIENCES
【注释】
[1]扩展X 射线吸收精细结构（extended X-ray absorption fine structure，EXAFS）。